As you can see by the previous post below this one, many of us use 5 inch heat duct pipe when outdoors. However, in your case I would use double wall chimney pipe, the kind used on gas and wood burning stoves. The reason being:
1) It's made to go though walls and keep the heat away from combustibles.
2) There are flanges and seals built for this pipe to keep weather and insects out of the wall.
3) Just incase you do have a fire you're not going to melt the pipe and burn your house down.
The only heat we had in the backwoods house I grew up in Washington was what we cut and burned in our cast iron wood stove. Chimney fires were always a threat so I grew up sleeping with my eyes closed and my nose awake. If you really want to go all the way, check into the commercial installation instructions that are available from Cookshack.