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Got my new 66 thursday and did the seasoning, Friday evening 10 pm started a butt. Placed on middle rack 225 thought to be around 10hrs +/- cook time. 10 hrs later 170, ended up cooking 15 hrs @ 225 and had internal temp of 185. The meat was perfect, noticed alot of you turn temp up later in the Q is this the proper way to reach the 195 target for butts. The only reason i did not let cook longer was that i had 5 racks of bbacks was Qing for dinner sat night they ended up great.
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There's no hard and fast rule as to a proper temp for smoking butts. 225 will buy you overnight smoking peace of mind on a 7-8 lb PB. If I'm in a hurry, I'll set the temp for 250. Generally I like to cook butts and briskets in the 240-250 range.

Some cooks will finish a butt, after the stall/plateau (165o) at a higher temp so as to build the crust. It's simply a matter of choice.

Your 66 (as wello as the smaller Cookshack electric smokers tend to build high moisture in the box. Excess mositure will hinder bark formation at 225 so one work-around is to open the door briefly every hour to dump steam.

As to internal temp, I look for tenderness. One guage is the blade bone. When it easily tugs free, you're done. This generally happens in the 185-195 range. If you're smoking a bone-out butt, probe it with a skewer. You're looking for minimal resistance. 190 is usually a safe bet as long as the probe isn't touching the bone.

Sounds like your 1st PB was a success.

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