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Grapevine is a recognized smoking medium. It is imperative, essential and absolutely a requirement that you never, ever use any wood that has been sprayed with a pesticide or herbicide. It will make you very sick. If you are certain that you neighbor's grapevine is "clean", try it out on a chickenb breast or two.

Donna
The spray might not be toxic, but might change the way the smoke smells and/or tastes. Perhaps burn a bit and see what you think.

Ask your friend what the name is of the spray he says "shouldn't harm the wood or grapes." If he says something like "BT" (a bacterial spray that only infects bugs) then you should be okay.

If it contains any "organophosphates" as in Malation or Parathion or any other stuff you don't recognize, stay clear. These are really nasty compounds.
I like grapevine. The bigger the "chunk" the better. I've tried fancy twigs from French vines but by far the best have been from a very, very old white grape vinyard in California. Chunks of vine big as regular chunks. Should be a very sweet smoke, excellent on pork, chicken even fish. I've also had some very funky Texas grapevine. It's important how it's stored. Very porous wood, I think it will mold fast.

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